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dc.contributor.authorBrieger, Lukas-
dc.contributor.authorHermann, Andreas-
dc.contributor.authorUnkelbach, Christian-
dc.contributor.authorStrohmann, Carsten-
dc.date.accessioned2020-05-07T07:49:05Z-
dc.date.available2020-05-07T07:49:05Z-
dc.date.issued2018-01-31-
dc.identifier.urihttp://hdl.handle.net/2003/39102-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-21020-
dc.description.abstractThe title compound, trimeth­yl(tetra­hydro­furan-κO)aluminium(III), [Al(CH3)3(C4H8O)], is an addition product of tri­methyl­aluminium and tetra­hydro­furan (THF). Instead of a dimeric structure, which is very common for these types of compounds, a monomeric mol­ecular structure is observed. The C—Al—C angles in the mol­ecule are very different from the C—Al—C angles found in dimeric mol­ecular structures, leading to a different symmetry around the AlIII atom. The reasons for these differences are discussed.en
dc.language.isoende
dc.relation.ispartofseriesActa Cryst. E;74(2)-
dc.rights.urihttps://creativecommons.org/licenses/by/2.0/uk/legalcode-
dc.subjectCrystal structureen
dc.subjectAluminiumen
dc.subjectTrimethylaluminiumen
dc.subjectTHFen
dc.subjectAdducten
dc.subjectMonomeren
dc.subjectAngleen
dc.subject.ddc540-
dc.titleCrystal structure and quantum-chemical calculations of a tri­methyl­aluminium–THF adducten
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access-
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1107/S2056989018001275de
eldorado.secondarypublication.primarycitationBrieger, Lukas, Andreas Hermann, Christian Unkelbach, und Carsten Strohmann. "Crystal structure and quantum-chemical calculations of a tri­methyl­aluminium–THF adduct." Acta Cryst. E 74, no. 2 (Februar 2018): 267-70.de
Appears in Collections:Lehrstühle für Anorganische Chemie

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