Langanzeige der Metadaten
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Brieger, Lukas | - |
dc.contributor.author | Hermann, Andreas | - |
dc.contributor.author | Unkelbach, Christian | - |
dc.contributor.author | Strohmann, Carsten | - |
dc.date.accessioned | 2020-05-07T07:49:05Z | - |
dc.date.available | 2020-05-07T07:49:05Z | - |
dc.date.issued | 2018-01-31 | - |
dc.identifier.uri | http://hdl.handle.net/2003/39102 | - |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-21020 | - |
dc.description.abstract | The title compound, trimethyl(tetrahydrofuran-κO)aluminium(III), [Al(CH3)3(C4H8O)], is an addition product of trimethylaluminium and tetrahydrofuran (THF). Instead of a dimeric structure, which is very common for these types of compounds, a monomeric molecular structure is observed. The C—Al—C angles in the molecule are very different from the C—Al—C angles found in dimeric molecular structures, leading to a different symmetry around the AlIII atom. The reasons for these differences are discussed. | en |
dc.language.iso | en | de |
dc.relation.ispartofseries | Acta Cryst. E;74(2) | - |
dc.rights.uri | https://creativecommons.org/licenses/by/2.0/uk/legalcode | - |
dc.subject | Crystal structure | en |
dc.subject | Aluminium | en |
dc.subject | Trimethylaluminium | en |
dc.subject | THF | en |
dc.subject | Adduct | en |
dc.subject | Monomer | en |
dc.subject | Angle | en |
dc.subject.ddc | 540 | - |
dc.title | Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | open access | - |
eldorado.secondarypublication | true | de |
eldorado.secondarypublication.primaryidentifier | https://doi.org/10.1107/S2056989018001275 | de |
eldorado.secondarypublication.primarycitation | Brieger, Lukas, Andreas Hermann, Christian Unkelbach, und Carsten Strohmann. "Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct." Acta Cryst. E 74, no. 2 (Februar 2018): 267-70. | de |
Enthalten in den Sammlungen: | Lehrstühle für Anorganische Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
---|---|---|---|---|
lh5865.pdf | 429.98 kB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource ist urheberrechtlich geschützt. |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons