Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Tymann, Dina Christina | - |
dc.contributor.author | Benedix, Lars | - |
dc.contributor.author | Iovkova, Lyuba | - |
dc.contributor.author | Pallach, Roman | - |
dc.contributor.author | Henke, Sebastian | - |
dc.contributor.author | Tymann, David | - |
dc.contributor.author | Hiersemann, Martin | - |
dc.date.accessioned | 2021-07-19T11:10:30Z | - |
dc.date.available | 2021-07-19T11:10:30Z | - |
dc.date.issued | 2020-05-28 | - |
dc.identifier.uri | http://hdl.handle.net/2003/40326 | - |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-22201 | - |
dc.description.abstract | We report on the implementation of the concept of a photochemically elicited two-carbon homologation of a π-donor–π-acceptor substituted chromophore by triple-bond insertion. Implementing a phenyl connector between the slide-in module and the chromophore enabled the synthesis of cylohepta[b]indole-type building blocks by a metal-free annulative one-pot two-carbon ring expansion of the five-membered chromophore. Post-irradiative structural elaboration provided founding members of the indolo[2,3-d]tropone family of compounds. Control experiments in combination with computational chemistry on this multibond reorganization process founded the basis for a mechanistic hypothesis. | en |
dc.language.iso | en | de |
dc.relation.ispartofseries | Chemistry - a european journal;Vol. 26. 2020, Issue 52, pp 11974-11978 | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.subject | Cascade reactions | en |
dc.subject | Cyclohepta[b]indole | en |
dc.subject | Indole[2,3-d]tropone | en |
dc.subject | Photochemistry | en |
dc.subject | Ring expansion | en |
dc.subject.ddc | 540 | - |
dc.title | Photochemical approach to the cyclohepta[b]indole scaffold by annulative two-carbon ring-expansion | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | open access | - |
eldorado.secondarypublication | true | de |
eldorado.secondarypublication.primaryidentifier | https://doi.org/10.1002/chem.202002581 | de |
eldorado.secondarypublication.primarycitation | Chemistry - a european journal. Vol. 26. 2020, Issue 52, pp 11974-11978 | en |
Appears in Collections: | Organische Chemie |
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chem.202002581.pdf | 1.2 MB | Adobe PDF | View/Open |
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