Autor(en): | Suter, Dieter Ernst, R. R. |
Titel: | Spin diffusion in resolved solid-state NMR spectra |
Sprache (ISO): | en |
Zusammenfassung: | Spectral spin diffusion in resolved solid-state NMR spectra is analyzed for various types of systems, including dipolar coupled spin-(1/2) systems in the presence of extraneous spins, and systems of quadrupolar spins with and without an additional dipolar reservoir. Diffusion of Zeeman and quadrupolar order via single-quantum and double-quantum spin-diffusion mechanisms is considered. Special attention is paid to the frequency offset dependence of the spin-diffusion rate. The theoretical predictions are verified by spin-diffusion measurements using two-dimensional spectroscopy techniques for 13C deuterium, and 14N resonance in single crystals. |
URI: | http://hdl.handle.net/2003/24995 http://dx.doi.org/10.17877/DE290R-3211 |
Herausgeberlink: | http://e3.physik.tu-dortmund.de/~suter/eprints/Spin_Diffusion.pdf |
Erscheinungsdatum: | 1985-11 |
Provinienz: | The American Physical Society |
URL: | http://prola.aps.org/pdf/PRB/v32/i9/p5608_1 |
Zitierform: | Suter, D; Ernst, R. R.: Spin diffusion in resolved solid state NMR spectra. In: Phys. Rev. B Vol. 32. 1985, Issue 9, pp 5608-5627. |
Enthalten in den Sammlungen: | Suter, Dieter Prof. Dr. |
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